Physics and measurement of time
Hyperfine transition
Also: hyperfijnovergang
A hyperfine transition is a tiny energy jump between two levels of an atom, caused by the interaction between the nuclear spin and the electron spin. Its frequency is extremely constant.
For caesium-133 that frequency is exactly 9,192,631,770 Hz, the value that defines the SI second. Atomic clocks (caesium, rubidium, hydrogen maser) measure precisely this transition.